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Probing weak force-induced parity violation by high-resolution mid-infrared molecular spectroscopy

Authors :
Clara Stoeffler
Benoît Darquié
Christophe Daussy
Frédéric Auguste
Anne Amy-Klein
Sean Tokunaga
Alexander Shelkovnikov
Christian Chardonnet
MMTF
Laboratoire de Physique des Lasers (LPL)
Université Paris 13 (UP13)-Centre National de la Recherche Scientifique (CNRS)-Université Paris 13 (UP13)-Centre National de la Recherche Scientifique (CNRS)
Université Paris 13 (UP13)-Centre National de la Recherche Scientifique (CNRS)
Groupe de spectrométrie moléculaire et atmosphérique (GSMA)
Université de Reims Champagne-Ardenne (URCA)-Centre National de la Recherche Scientifique (CNRS)
P. N. Lebedev Physical Institute of the Russian Academy of Sciences [Moscow] (LPI RAS)
Russian Academy of Sciences [Moscow] (RAS)
ANR NCPCHEM 2010 BLAN 724 3
Source :
Molecular Physics, Molecular Physics, Taylor & Francis, 2013, 111 (14-15), pp.2363-2373
Publication Year :
2013
Publisher :
Informa UK Limited, 2013.

Abstract

International audience; To date no experiment has reached the level of sensitivity required to observe weak nuclear force induced parity violation (PV) energy differences in chiral molecules. In this paper, we present the approach, adopted at Laboratoire de Physique des Lasers (LPL), to measure frequency differences in the vibrational spectrum of enantiomers. We review different spectroscopic methods developed at LPL leading to the highest resolutions, as well as 20 years of CO2 laser stabilization work enabling such precise measurements. After a first attempt to observe PV vibrational frequency shifts using sub-Doppler saturated absorption spectroscopy in a cell, we are currently aiming at an experiment based on Doppler-free two-photon Ramsey interferometry on a supersonic beam. We report on our latest progress towards observing PV with chiral organo-metallic complexes containing a heavy rhenium atom.

Details

ISSN :
13623028 and 00268976
Volume :
111
Database :
OpenAIRE
Journal :
Molecular Physics
Accession number :
edsair.doi.dedup.....dc978ae14d830b72f89286000964c3ec
Full Text :
https://doi.org/10.1080/00268976.2013.821186