Supramolecular isomerism, single-crystal to single-crystal transformation induced by release of in situ generated I2 between two supramolecular frameworks

Authors :: Min Zhu
Xing Meng
Shu Na Zhao
Zhaomin Hao
Sheng Qun Su
Xue Zhi Song
Shu Yan Song
Hongjie Zhang
Source :: Dalton Transactions. 42:5619
Publication Year :: 2013
Publisher :: Royal Society of Chemistry (RSC), 2013.
Abstract: Two supramolecular isomers, [H2tpim·H4betc]·I (1) and [H2tpim·H4betc]·I3·2H2O (2), have been synthesized by one-pot reactions. Single-crystal to single-crystal transformations are observed between the two supramolecular isomers which are induced by release of in situ generated I2.

Subjects :: Inorganic Chemistry
In situ
Crystallography
Materials science
Inorganic chemistry
Supramolecular chemistry
Metal-organic framework
Single crystal
Layer (electronics)
Transformation (music)

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