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Rh-catalyzed tunable defluorinative borylation
- Source :
- Chemical communications (Cambridge, England). 57(58)
- Publication Year :
- 2021
-
Abstract
- Described herein is a Rh-catalyzed tunable defluorinative borylation of allylic gem-difluorides to provide allylborylated monofluoroalkenes or homoallylborylated monofluoroalkenes with excellent Z/E selectivities. Completely different reaction paths were observed by slightly changing the reaction conditions. Allylborylated monofluoroalkenes were further converted into dihydroxyl-containing monofluoroalkenes.
Details
- ISSN :
- 1364548X
- Volume :
- 57
- Issue :
- 58
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....e7af9820e16e19a1f40256192cb3731c