Back to Search
Start Over
Gyroidal metal-organic frameworks
- Source :
- Journal of the American Chemical Society. 134(1)
- Publication Year :
- 2011
-
Abstract
- The gyroid is ubiquitous for underlying the construction of natural substance and artificial zeolites, but it has been, surprisingly, overlooked by chemists who work in the field of metal-organic frameworks (MOFs). In this work, a series of gyroidal MOFs with gie topology, constructed from 1,2-bis((5H-imidazol-4-yl)methylene)hydrazine and octahedral metal ions, such as Zn(II), Mn(II), Cu(II), and Ni(II), have been synthesized. The Zn(II) analogue, named as STU-1, shows exceptional thermal and chemical stabilities, and exhibits permanent porosity and CO(2) capture ability.
- Subjects :
- Models, Molecular
Metal ions in aqueous solution
Inorganic chemistry
Hydrazine
Molecular Conformation
General Chemistry
Biochemistry
Catalysis
chemistry.chemical_compound
Colloid and Surface Chemistry
Hydrazines
chemistry
Octahedron
Polymer chemistry
Organometallic Compounds
Metal-organic framework
Adsorption
Methylene
Porosity
Topology (chemistry)
Gyroid
Subjects
Details
- ISSN :
- 15205126
- Volume :
- 134
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....e85956e3714ae4c67a01fb75bde28390