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Dual-Emission Ratiometric Fluorescent Probe Based on Lanthanide-Functionalized Carbon Quantum Dots for White Light Emission and Chemical Sensing
- Source :
- ACS Omega, ACS Omega, Vol 6, Iss 22, Pp 14629-14638 (2021)
- Publication Year :
- 2021
- Publisher :
- American Chemical Society, 2021.
-
Abstract
- Herein, we develop a novel method to synthesize lanthanide-functionalized carbon quantum dots via free-radical copolymerization using the methyl methacrylate (MMA) monomer as a functional monomer and introducing a lanthanide complex to obtain the dual-emission fluorescent composite material FCQDs-Ln(TFA)3 (Ln = Eu, Tb; TFA: trifluoroacetylacetone). The obtained composites were fully characterized, and their structures were investigated by Fourier transform infrared spectroscopy (FTIR), 1H NMR spectroscopy, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). Subsequently, a series of white-light-emitting polymer composite films FCQDs- (Eu:Tb)(TFA)3/poly(methyl methacrylate) (PMMA) were designed and synthesized by adjusting the ratio of Eu(TFA)3/Tb(TFA)3 under different wavelengths. More significantly, FCQDs-Tb(TFA)3 was selected as a sensitive probe for sensing metal cations due to excellent photoluminescence properties, revealing a unique capability of FCQDs-Tb(TFA)3 of detecting Fe(III) cations with high efficiency and selectivity. Furthermore, the sensing experiment results indicated that FCQDs-Tb(TFA)3 is ideal as a fluorescent nanoprobe for Fe3+ ion detection, and the lowest detection limit for Fe3+ is 0.158 μM, which is superior to many other previous related research studies. This pioneering work provides a new idea and method for constructing a dual-emission ratio sensor based on carbon quantum dots and also extends the potential application in the biological and environmental fields.
- Subjects :
- Lanthanide
Photoluminescence
Materials science
General Chemical Engineering
Nanoprobe
General Chemistry
Fluorescence
Article
chemistry.chemical_compound
Chemistry
Monomer
chemistry
X-ray photoelectron spectroscopy
Physical chemistry
Methyl methacrylate
Fourier transform infrared spectroscopy
QD1-999
Subjects
Details
- Language :
- English
- ISSN :
- 24701343
- Volume :
- 6
- Issue :
- 22
- Database :
- OpenAIRE
- Journal :
- ACS Omega
- Accession number :
- edsair.doi.dedup.....eb327632bc1aae0cbcb30e95574637d4