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On-surface photo-dissociation of C–Br bonds: towards room temperature Ullmann coupling
- Source :
- Chemical Communications. 51:12593-12596
- Publication Year :
- 2015
- Publisher :
- Royal Society of Chemistry (RSC), 2015.
-
Abstract
- The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.
- Subjects :
- Materials Chemistry2506 Metals and Alloys
Materials science
Surfaces, Coatings and Film
Ceramics and Composite
Surface order
Photochemistry
Catalysis
Dissociation (chemistry)
Catalysi
law.invention
Coatings and Films
chemistry.chemical_compound
X-ray photoelectron spectroscopy
law
Electronic
Materials Chemistry
Chemistry (all)
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films
2506
Optical and Magnetic Materials
Materials Chemistry2506 Metals and Alloy
Reaction conditions
Electronic, Optical and Magnetic Material
Metals and Alloys
Halogenation
General Chemistry
Surfaces
Tetracene
chemistry
Scanning tunneling microscope
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....ef2cb3a5492aa73b0c44e66bc4a96971