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Direct asymmetric hydrogenation of α-keto acids by using the highly efficient chiral spiro iridium catalysts
- Source :
- Chem. Commun.. 50:15987-15990
- Publication Year :
- 2014
- Publisher :
- Royal Society of Chemistry (RSC), 2014.
-
Abstract
- A new efficient and highly enantioselective direct asymmetric hydrogenation of α-keto acids employing the Ir/SpiroPAP catalyst under mild reaction conditions has been developed. This method might be feasible for the preparation of a series of chiral α-hydroxy acids on a large scale.
- Subjects :
- inorganic chemicals
Noyori asymmetric hydrogenation
chemistry.chemical_element
Stereoisomerism
Iridium
Catalysis
Materials Chemistry
Organic chemistry
Spiro Compounds
Reaction conditions
Chemistry
organic chemicals
Asymmetric hydrogenation
Metals and Alloys
Enantioselective synthesis
Glyoxylates
General Chemistry
Keto Acids
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Mandelic Acids
Hydrogenation
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 50
- Database :
- OpenAIRE
- Journal :
- Chem. Commun.
- Accession number :
- edsair.doi.dedup.....f25ce50e6bcd953b6af1272a9129ab38