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Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2015, 51 (80), pp.14859-14861. ⟨10.1039/C5CC06054K⟩
- Publication Year :
- 2015
- Publisher :
- HAL CCSD, 2015.
-
Abstract
- International audience; We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.
- Subjects :
- Nanotechnology
010402 general chemistry
Photochemistry
complex mixtures
01 natural sciences
Catalysis
Ion
Calixarene
Materials Chemistry
Molecule
[CHIM]Chemical Sciences
cardiovascular diseases
010405 organic chemistry
Chemistry
Metals and Alloys
General Chemistry
Chromophore
musculoskeletal system
0104 chemical sciences
3. Good health
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Photoexcitation
Molecular shuttle
Ceramics and Composites
cardiovascular system
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2015, 51 (80), pp.14859-14861. ⟨10.1039/C5CC06054K⟩
- Accession number :
- edsair.doi.dedup.....f3df93b465cbe3429aa6386e1d5d385a
- Full Text :
- https://doi.org/10.1039/C5CC06054K⟩