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Palladium-Catalyzed Selective Generation of CO from Formic Acid for Carbonylation of Alkenes
- Source :
- Journal of the American Chemical Society. 140:5217-5223
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- A general and selective palladium-catalyzed alkoxycarbonylation of all kinds of alkenes with formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra-substituted including functionalized olefins are converted into linear esters with high yields and regioselectivity. Key-to-success is the use of specific palladium catalysts containing ligands with built-in base, e.g., L5. Comparison experiments demonstrate that the active catalyst system not only facilitates isomerization and carbonylation of alkenes but also promotes the selective decomposition of HCOOH to CO under mild conditions.
- Subjects :
- chemistry.chemical_classification
Base (chemistry)
010405 organic chemistry
Formic acid
chemistry.chemical_element
Regioselectivity
General Chemistry
010402 general chemistry
01 natural sciences
Biochemistry
Decomposition
Catalysis
0104 chemical sciences
chemistry.chemical_compound
Colloid and Surface Chemistry
chemistry
Organic chemistry
Carbonylation
Isomerization
Palladium
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 140
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....f655fa8fa88aa57dd5e482d0fe40a407