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Enhanced stereoselectivity in the catalytic dihydroxylation of acyclic allylic alcohols
- Publication Year :
- 2016
-
Abstract
- A series of acyclic allylic alcohols were oxidised with catalytic osmium tetroxide. Use of dichloromethane as solvent and trimethylamine-N-oxide dihydrate as the reoxidant (Poli's conditions) gave levels of stereoselectivity that were superior to those found under more conventional oxidising conditions.
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....f6d8d39e53cf6f96f8540d427a3b7ef8