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Palladium-Catalyzed Regio- and Enantioselective Allylic Alkylation of Bis Allylic Carbonates Derived from Morita−Baylis−Hillman Adducts
- Source :
- Organic Letters. 9:3961-3964
- Publication Year :
- 2007
- Publisher :
- American Chemical Society (ACS), 2007.
-
Abstract
- Morita-Baylis-Hillman diene adducts are used as substrates in the palladium-catalyzed asymmetric allylic alkylation reaction with oxygen and carbon nucleophiles in good regio- and enantioselectivity.
- Subjects :
- Models, Molecular
inorganic chemicals
Allylic rearrangement
Alkylation
Molecular Structure
Diene
Organic Chemistry
Carbonates
Enantioselective synthesis
chemistry.chemical_element
Stereoisomerism
Biochemistry
Medicinal chemistry
Catalysis
Adduct
Oxygen
chemistry.chemical_compound
Tsuji–Trost reaction
Nucleophile
chemistry
Physical and Theoretical Chemistry
Palladium
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 9
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....f9091250bfae7320d72fe6cacf0c5150