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Origin and transformation of light hydrocarbons ascending at an active pockmark on Vestnesa Ridge, Arctic Ocean
- Publication Year :
- 2020
- Publisher :
- AGU, 2020.
-
Abstract
- We report on the geochemistry of hydrocarbons and pore waters down to 62.5 mbsf, collected by drilling with the MARUM‐MeBo70 and by gravity coring at the Lunde pockmark in the Vestnesa Ridge. Our data document the origin and transformations of volatiles feeding gas emissions previously documented in this region. Gas hydrates are present where a fracture network beneath the pockmark focusses migration of thermogenic hydrocarbons characterized by their C1/C2+ and stable isotopic compositions (δ2H‐CH4, δ13C‐CH4). Measured geothermal gradients (~80°C km‐1) and known formation temperatures (>70°C) suggest that those hydrocarbons are formed at depths >800 mbsf. A combined analytical/modeling approach, including concentration and isotopic mass balances, reveals that pockmark sediments experience diffuse migration of thermogenic hydrocarbons. However, at sites without channeled flow this appears to be limited to depths > ~50 mbsf. At all sites we document a contribution of microbial methanogenesis to the overall carbon cycle that includes a component of secondary carbonate reduction (CR) – i.e. reduction of dissolved inorganic carbon (DIC) generated by anaerobic oxidation of methane (AOM) in the uppermost methanogenic zone. AOM and CR rates are spatially variable within the pockmark and are highest at high‐flux sites. These reactions are revealed by 13C‐DIC depletions at the sulfate‐methane interface at all sites. However, 13C‐CH4 depletions are only observed at the low methane flux sites because changes in the isotopic composition of the overall methane pool are masked at high‐flux sites. 13C‐depletions of TOC suggest that at seeps sites, methane‐derived carbon is incorporated into de novo synthesized biomass.
- Subjects :
- VDP::Mathematics and natural science: 400::Geosciences: 450
010504 meteorology & atmospheric sciences
Pockmark
Clathrate hydrate
Geochemistry
010502 geochemistry & geophysics
01 natural sciences
Methane
Light hydrocarbons
chemistry.chemical_compound
Geophysics
Arctic
chemistry
13. Climate action
Space and Planetary Science
Geochemistry and Petrology
VDP::Matematikk og Naturvitenskap: 400::Geofag: 450
Earth and Planetary Sciences (miscellaneous)
Ridge (meteorology)
14. Life underwater
Geology
0105 earth and related environmental sciences
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....fab1a044998fa3f54722f06161ff4e2d
- Full Text :
- https://doi.org/10.1029/2018JB016679