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Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents
- Source :
- Organic Letters. 10:2299-2302
- Publication Year :
- 2008
- Publisher :
- American Chemical Society (ACS), 2008.
-
Abstract
- Catalytic amounts of aromatic carboxylic acid MesCO H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation-metalation mechanism.
- Subjects :
- inorganic chemicals
chemistry.chemical_classification
C h bond
010405 organic chemistry
Carboxylic acid
Organic Chemistry
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Biochemistry
0104 chemical sciences
Ruthenium
Catalysis
chemistry
Organic chemistry
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 10
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....fddcfa449ef4448b841664f1469903ad
- Full Text :
- https://doi.org/10.1021/ol800773x