Back to Search
Start Over
The effects of temperature and molten salt on solar pyrolysis of lignite
- Source :
- Energy, Energy, Elsevier, 2019, 181, pp.407-416. ⟨10.1016/j.energy.2019.05.181⟩
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- International audience; Molten salt pyrolysis driven by concentrated solar radiation is well positioned to utilize solar energy and lignite effectively. This study focused on the effects of temperature (500, 600, 700 and 800 °C) and molten carbonate salt (Li2CO3-Na2CO3-K2CO3) on properties of char obtained from lignite pyrolysis, as well as gas and tar products for revealing their formation mechanism and transformation process. Molten salt pyrolysis of HulunBuir lignite produced more gas products and less char compared to conventional pyrolysis owing to the enhanced heat transfer and catalytic effect of molten salt. The char yield decreased from 58.4% to 43.4%, and the gas yield (especially CO2, H2 and CO) increased from 28.3% to 46.1% at 800 °C. CO2, CO and H2 production increased about 60.43%, 103.42% and 65.2% at 800 °C, respectively. Additionally, the presence of molten salt improved the tar quality with more hydrocarbon content (maximum increase of 5.8%) and less oxygenated compounds. The structure and reactivity relationship of char was characterized by XRD, BET, SEM, FTIR, Raman spectroscopy and TGA. Molten salt generated char had a higher reactivity due to the increase of disorder, surface area, microporosity (maximum of 71.74%) and active sites.
- Subjects :
- 020209 energy
Salt (chemistry)
02 engineering and technology
7. Clean energy
Industrial and Manufacturing Engineering
Solar pyrolysis
[SPI]Engineering Sciences [physics]
chemistry.chemical_compound
020401 chemical engineering
0202 electrical engineering, electronic engineering, information engineering
Reactivity (chemistry)
Lignite
Char
0204 chemical engineering
Electrical and Electronic Engineering
Molten salt
Civil and Structural Engineering
chemistry.chemical_classification
Chemistry
Mechanical Engineering
Temperature
Tar
Building and Construction
Pollution
Char properties
General Energy
Hydrocarbon
Chemical engineering
13. Climate action
Carbonate
Pyrolysis
Subjects
Details
- ISSN :
- 03605442
- Volume :
- 181
- Database :
- OpenAIRE
- Journal :
- Energy
- Accession number :
- edsair.doi.dedup.....ffb7e5d8ddb702e64e944105180bfc9b