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Improving Cathodes with a Polymer Interlayer in Reversed Organic Solar Cells
- Source :
- Advanced Energy Materials. 4:1400643
- Publication Year :
- 2014
- Publisher :
- Wiley, 2014.
-
Abstract
- The effects of cathode modification by a conjugated polymer interlayer PFPA1on the performance of reversed organic solar cells (substrate/cathode/active layer/transparent anode) based on different active material systems and different substrate electrodes are systematically investigated. A reduction of the work function irrespective of the substrate cathode used is observed upon the deposition of the PFPA1 interlayer, which is further related to an improved built-in electric field and open-circuit voltage. The amphiphilic character of the PFPA1 interlayer alters the surface energy of the substrate cathode,leading to the formation of a better active layer morphology aiding efficient exciton dissociation and photocurrent extraction in the modified solar cells.Hence, internal quantum efficiency is found to be significantly higher than that of their unmodified counterparts, while optically, the modified and unmodified solar cells are identical. Moreover, the deep highest occupied molecular orbital (HOMO) of the PFPA1 interlayer improves the selectivity for all investigated substrate cathodes, thus enhancing the fi ll factor. Refereed/Peer-reviewed
- Subjects :
- Materials science
interlayer modification
Organic solar cell
Renewable Energy, Sustainability and the Environment
selectivity
Substrate (chemistry)
organic solar cells
Hybrid solar cell
Quantum dot solar cell
Cathode
Polymer solar cell
law.invention
Anode
interfaces
Chemical engineering
law
General Materials Science
Work function
polymer solar cells
Subjects
Details
- ISSN :
- 16146832
- Volume :
- 4
- Database :
- OpenAIRE
- Journal :
- Advanced Energy Materials
- Accession number :
- edsair.doi.dedup.....ffd352350857c0f87e5e27f153f33362