Absorption of nitric oxide into aqueous solutions of ferrous chelates accompanied by instantaneous reaction

The absorption of nitric oxide (NO) into aqueous solutions of ferrous chelates of nitrilotriacetic acid (NTA), ethylene diaminetetraacetic acid (EDTA), hydroxyethylenediaminetriacetic acid (HEDTA), and diethylenetriaminepentaacetic acid (DTPA) was studied in a stirred cell reactor. Experimental conditions were as follows: 0.05 less than or equal to CF(IIL) less than or equal to 0.1 kmol/mg(3), 8 less than or equal to P-NO less than or equal to 30 kPa, 3 less than or equal to pH less than or equal to 10 (NTA), or 7 less than or equal to pH less than or equal to 8 (EDTA, HEDTA, DTPA), C-L less than or equal to C-Fe(II) less than or equal to 3C(L) (NTA) or C-L = C-Fe(II) (EDTA, HEDTA, DTPA), and 293 less than or equal to T less than or equal to 333 K (NTA, EDTA, HEDTA) or T = 294 K (DTPA). The absorption leads to stable ferrous NO chelates. Due to the high reaction rate, in combination with the relatively high P-NO applied, the absorption rate is strongly affected by mass transfer limitation only. By applying penetration theory, the ratio of the diffusion coefficients of ferrous chelates and NO was determined: at T = 294 K (D(Fe(II)chelate)/D-NO)(1/2) = 0.44 +/- 0.01, 0.34 +/- 0.01, 0.36 +/- 0.01, and 0.31 +/- 0.015, for the ferrous NTA, HEDTA, EDTA, and DTPA complexes, respectively. At elevated T, (D(Fe(II)chelate)/D-NO)(1/2) decreases due to the unusual T-dt pendency of D-NO. For ferrous NTA, the formation of the ferrous NO chelate is;accompanied by pH effects that can be understood from iron chelate chemistry. In the case of ferrous NTA, pH