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Electronic Structure of Pt and Pt-Co Nanoparticles with O2 and O2/H2O Adsorption Revealed by In Situ XAFS and Hard X-ray Photoelectron Spectroscopy
- Source :
- ECS Transactions. 72(8):131-136
- Publication Year :
- 2016
- Publisher :
- The Electrochemical Society, 2016.
-
Abstract
- The electronic structures of Pt and Pt-Co nanoparticles with O2 adsorption and O2/H2O co-adsorption were investigated by in situ hard X-ray photoelectron spectroscopy (HAXPES) and in situ high resolution fluorescence detection X-ray absorption spectroscopy (HERFD-XAS) to clarify the effects of water adsorption on fuel cell cathode catalysis surface. The experimental results suggest that under the pressure of 1 mbar, the adsorption of H2O hinders the successive O2 adsorption on Pt surface, while under the pressure of 1 bar, the adsorption of H2O enhances the adsorption of O2 on Pt surface. This water effect is found to be more significant on Pt surface than on Pt-Co surface. These results would be helpful to understand how the water affects the fuel cell performance and why Pt-Co nanoparticles show higher oxygen reduce reaction (ORR) activity than Pt nanoparticles.
Details
- Language :
- English
- Volume :
- 72
- Issue :
- 8
- Database :
- OpenAIRE
- Journal :
- ECS Transactions
- Accession number :
- edsair.jairo.........4b2bfd88798f1bb2d769441afad924b3