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Electrochemical Formation of Ca-Si in Molten CaCl2-KCl
- Source :
- Journal of The Electrochemical Society. 162(4):D186-D191
- Publication Year :
- 2015
- Publisher :
- The Electrochemical Society, 2015.
-
Abstract
- Electrochemical formation of a Ca-Si film in a molten CaCl2-KCl at 923 K was investigated. Potentiostatic electrolysis of a Si electrode at −0.10 V for 1 h resulted in the formation of a multiphase Ca-Si film having a thickness of about 30 μm. The Ca-Si film was converted into other alloy phases by anodic potentiostatic electrolysis after the cathodic electrodeposition of Ca metal at −0.10 V. The various transformation reactions and the corresponding equilibrium potentials were clarified. At 923 K, the equilibrium potential was found to be 0.18 V (CaSi2). Reflectance measurements in the ultraviolet, visible, and near-infrared region clarified that the CaSi2 film has a direct bandgap of 3.1 eV.
Details
- Language :
- English
- ISSN :
- 00134651
- Volume :
- 162
- Issue :
- 4
- Database :
- OpenAIRE
- Journal :
- Journal of The Electrochemical Society
- Accession number :
- edsair.jairo.........8dcce6a4f795288fcb2ce31043dc64d1