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Photocatalytic Synthesis of p-Anisaldehyde in a Mini Slurry-Bubble Reactor under Solar Light Irradiation
- Source :
- The Canadian Journal of Chemical Engineering. 98(1):119-126
- Publication Year :
- 2019
- Publisher :
- John Wiley & Sons, Inc., 2019.
-
Abstract
- Dense photocatalyst slurry was employed for the synthesis of p‐anisaldehyde under solar light irradiation. An Fe‐modified rutile TiO 2 (Fe‐TiO 2, 34.5 m 2/g) photocatalyst was used as a visible‐light‐responsive photocatalyst. A conventional TiO 2 (P25, 35 m 2/g) photocatalyst was also examined as a reference catalyst. XRD patterns and diffuse reflectance spectra showed that Fe‐TiO 2 consists of 100 % rutile phase and absorbs more visible light compared to P25, respectively. The catalyst powder was suspended in an ethyl acetate solution of p‐methoxytoluene in the mini‐reactor, with oxygen bubbling, under a solar simulator, visible light, and UV LEDs. p‐anisaldehyde, as a reaction product, was analyzed by sampling using gas‐chromatograph. Regardless of the light source, Fe‐TiO 2 always outperformed P25 in terms of both generation rates (GR) of p‐anisaldehyde and energy requirements (ER). It was demonstrated that the highly dense Fe‐TiO 2 slurry was efficient for the synthesis under solar light owing to the small size of the reactor. The small amount of Pt and ZrO 2 cocatalysts significantly enhanced the GR under solar light. By adopting a visible light responsive Fe‐TiO 2 photocatalyst, the mini slurry‐bubble reactor under solar light achieved a high GR per catalyst mass (CM), which is one to two orders higher than that reported by most previous studies with high‐power lamps.
- Subjects :
- titanium dioxide
organic synthesis
mini reactor
photocatalysis
solar light
Subjects
Details
- Language :
- English
- ISSN :
- 1939019X
- Volume :
- 98
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- The Canadian Journal of Chemical Engineering
- Accession number :
- edsair.jairo.........e3b6b4e1e2cdb7624be3aaf6d32a7027