Effect of Electron Beam Irradiation on Surface Dielectric Properties of Polymeric Materials

Секция 3. Модификация свойств материалов = Section 3. Modification of Material Properties The polymeric materials could degrade due to the electron irradiation, photo-irradiation and heat effect following with the surface flashover in vacuum. On the other hand, the surface insulating performance could be improved by electron irradiation. In order to study the effect of electron irradiation on the insulating materials, the surface parameters were measured and the flashover experiment was performed in vacuum after electron beam irradiation. First, several typical polymeric samples, such as polytetrafluoroethylene (PTFE), polymethylmethacrylate (PMMA) and polyamide (PA6), were exposed by different energy electron beam from 10 keV to 30 keV and in different radiation times. Then the surface parameters, such as surface topography, chemical group and surface roughness, were measured for insulating samples in different processing conditions. Since the surface trap distribution is closely related to the microscopic structure and defects, the trap parameters of PA6 samples were deduced based on the surface potential data. In this measurement, the polymeric surface was charged by needle-to-plane corona discharge, and then the surface potential was measured by Kelvin electrostatic probe. The surface flashover experiment in vacuum was performed using finger-type plane-electrodes, and the relationship between electron beam energy, irradiation time, and flashover voltage was analyzed. The experiment results indicate that the surface trap energy level is deeper and the trap density is greater after electron irradiation, and the surface flashover voltages for several materials are also improved to different degrees. Combined the macroscopic dielectric parameters with the microscopic one, the effect of electron irradiation on surface insulating property was analyzed.