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Persistence of the valence bond glass state in the double perovskites Ba2−xSrxYMoO6

Authors :
McLaughlin, Abbie
de Vries, Mark A.
Bos, J-W G.
Source :
McLaughlin, A, de Vries, M A & Bos, J-W G 2010, ' Persistence of the valence bond glass state in the double perovskites Ba2−xSrxYMoO6 ', Physical review B: Condensed matter and materials physics, vol. 82, no. 9, 094424, pp.-. https://doi.org/10.1103/PhysRevB.82.094424
Publication Year :
2010

Abstract

The Ba2−xSrxYMoO6 double perovskites with a geometrically frustrated face centered Mo5+ s = 1/2 sublattice have been investigated using neutron powder-diffraction, magnetic-susceptibility, and heat-capacity measure-ments. Reduction in the average A-site radius results in the distortion of the crystal structure from cubic for x = 0 to monoclinic for x = 2 without affecting the Y/Mo inversion (condense into spin singlets as previously observed for Ba2YMoO6, leaving a small fraction of the spins isolated or only weak ferromagnetically coupled to each other.

Details

Language :
English
Database :
OpenAIRE
Journal :
McLaughlin, A, de Vries, M A & Bos, J-W G 2010, ' Persistence of the valence bond glass state in the double perovskites Ba2−xSrxYMoO6 ', Physical review B: Condensed matter and materials physics, vol. 82, no. 9, 094424, pp.-. https://doi.org/10.1103/PhysRevB.82.094424
Accession number :
edsair.od......3094..15723c6d7b6f5d79569ae683954e36c0
Full Text :
https://doi.org/10.1103/PhysRevB.82.094424