Protecting-group-free

Authors :: Gao-Lan, Zhang
Madhusudhan Reddy, Gadi
Xikai, Cui
Ding, Liu
Jiabin, Zhang
Varma, Saikam
Christopher, Gibbons
Peng G, Wang
Lei, Li
Source :: Green Chem
Publication Year :: 2021
Abstract: A facile and green S-glycosylation method has been developed featuring protecting-group-free and proceeding-in-water like enzymatic synthesis. Glycosylation of fluoride donors with thiol sugar acceptors using Ca(OH)(2) as a promoter afforded various thioglycosides in good yields with exclusive stereoselectivity. This method also enabled the successful production of S-linked oligosaccharides and S-linked glycopeptides.

ISSN :: 14639262
Volume :: 23
Issue :: 8
Database :: OpenAIRE
Journal :: Green chemistry : an international journal and green chemistry resource : GC
Accession number :: edsair.pmid..........21c533f969585324cc2de67df213a40e

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