An unprecedented {Ni

Authors :: Grégoire, Paille
Amandine, Boulmier
Alexandre, Bensaid
Minh-Huong, Ha-Thi
Thu-Trang, Tran
Thomas, Pino
Jérôme, Marrot
Eric, Rivière
Christopher H, Hendon
Olivier, Oms
Maria, Gomez-Mingot
Marc, Fontecave
Caroline, Mellot-Draznieks
Anne, Dolbecq
Pierre, Mialane
Source :: Chemical communications (Cambridge, England). 55(29)
Publication Year :: 2019
Abstract: A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.

Tools