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$\Lambda$-doublet spectra of diatomic radicals and their dependence on fundamental constants

Authors :
Kozlov, M. G.
Source :
Phys.Rev.A, 80, 022118 (2009)
Publication Year :
2009

Abstract

$\Lambda$-doublet spectra of light diatomic radicals have high sensitivity to the possible variations of the fine structure constant alpha and electron-to-proton mass ratio beta. For molecules OH and CH sensitivity is further enhanced because of the J-dependent decoupling of the electron spin from the molecular axis, where J is total angular momentum of the molecule. When $\Lambda$-splitting has different signs in two limiting coupling cases a and b, decoupling of the spin leads to the change of sign of the splitting and to the growth of the dimensionless sensitivity coefficients. For example, sensitivity coefficients for the $\Lambda$-doublet lines J=9/2 of the $\Pi_{1/2}$ state of OH molecule are on the order of $10^3$.<br />Comment: 10 pages, 4 tables, 3 figures; v2: figures added, discussion of quadrupole interaction added

Details

Database :
arXiv
Journal :
Phys.Rev.A, 80, 022118 (2009)
Publication Type :
Report
Accession number :
edsarx.0905.1714
Document Type :
Working Paper
Full Text :
https://doi.org/10.1103/PhysRevA.80.022118