Back to Search Start Over

Experimental evidence of enhanced transport in supernematics

Authors :
Kipnusu, Wycliffe K.
Zeigermann, Philipp
Iacob, Ciprian
Kremer, Friedrich
Schoen, Martin
Mazza, Marco G.
Valiullin, Rustem
Publication Year :
2014

Abstract

Deviations of molecular shapes from spherical symmetry may give rise to a variety of novel phenomena, including their dynamic behavior. It has recently been predicted [Mazza \textit{et al}. Phys. Rev. Lett. \textbf{105}, 227802 (2010)] that liquid crystals in the reentrant nematic phases may show unexpectedly high rates of translational displacements. Using broadband dielectric spectroscopy and a single-component thermotropic liquid crystal we explore molecular dynamics in the vicinity of the reentrant nematic transition and find the formation of a maximum in the mobilities upon changing temperature. The occurrence of the high mobility states are found to be history-dependent due to the formation of metastable mesophases on heating. The experimental results are further supported by computer simulation. Our results contribute to the clarification of an ongoing controversy on the dynamics of reentrant nematics.

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.1406.5868
Document Type :
Working Paper