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Characterization of the non-Arrhenius behavior of supercooled liquids by modeling non-additive stochastic systems
- Source :
- Phys. Rev. E 100, 022139 (2019)
- Publication Year :
- 2019
-
Abstract
- The characterization of the formation mechanisms of amorphous solids is a large avenue for research, since understanding its non-Arrhenius behavior is challenging to overcome. In this context, we present one path toward modeling the diffusive processes in supercooled liquids near glass transition through a class of non-homogeneous continuity equations, providing a consistent theoretical basis for the physical interpretation of its non-Arrhenius behavior. More precisely, we obtain the generalized drag and diffusion coefficients that allow us to model a wide range of non-Arrhenius processes. This provides a reliable measurement of the degree of fragility of the system and an estimation of the fragile-to-strong transition in glass-forming liquids, as well as a generalized Stokes-Einstein equation, leading to a better understanding of the classical and quantum effects on the dynamics of non-additive stochastic systems.
- Subjects :
- Condensed Matter - Statistical Mechanics
Subjects
Details
- Database :
- arXiv
- Journal :
- Phys. Rev. E 100, 022139 (2019)
- Publication Type :
- Report
- Accession number :
- edsarx.1903.03156
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1103/PhysRevE.100.022139