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Characterization of the non-Arrhenius behavior of supercooled liquids by modeling non-additive stochastic systems

Authors :
Junior, Antonio Cesar do Prado Rosa
Cruz, Clebson
Santana, Wanisson Silva
Moret, Marcelo Albano
Source :
Phys. Rev. E 100, 022139 (2019)
Publication Year :
2019

Abstract

The characterization of the formation mechanisms of amorphous solids is a large avenue for research, since understanding its non-Arrhenius behavior is challenging to overcome. In this context, we present one path toward modeling the diffusive processes in supercooled liquids near glass transition through a class of non-homogeneous continuity equations, providing a consistent theoretical basis for the physical interpretation of its non-Arrhenius behavior. More precisely, we obtain the generalized drag and diffusion coefficients that allow us to model a wide range of non-Arrhenius processes. This provides a reliable measurement of the degree of fragility of the system and an estimation of the fragile-to-strong transition in glass-forming liquids, as well as a generalized Stokes-Einstein equation, leading to a better understanding of the classical and quantum effects on the dynamics of non-additive stochastic systems.

Details

Database :
arXiv
Journal :
Phys. Rev. E 100, 022139 (2019)
Publication Type :
Report
Accession number :
edsarx.1903.03156
Document Type :
Working Paper
Full Text :
https://doi.org/10.1103/PhysRevE.100.022139