Equivalent circuit model for electrosorption with redox active materials

Electrosorption is a promising technique for brackish water deionization and waste water remediation. Faradaic materials with redox activity have recently been shown to enhance both the adsorption capacity and the selectivity of electrosorption processes. Development of the theory of electrosorption with redox active materials can provide a fundamental understanding of the electrosorption mechanism and a means to extract material properties from small-scale experiments for process optimization and scale-up. Here, we present an intuitive, physics-based equivalent circuit model to describe the electrosorption performance of redox active materials, which is able to accurately fit experimental cyclic voltammetry measurements. The model can serve as an efficient and easy-to-implement tool to evaluate properties of redox active materials and help to distinguish between the transport-limited and reaction-limited regimes in electrosorption processes. And the extracted intrinsic material properties can be further incorporated into process models under lower supporting electrolyte concentrations for realistic electrosorption applications.
Comment: 26 pages, 8 figures