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Single crystal growth and physical properties of pyroxene CoGeO$_3$

Authors :
Zhao, L.
Hu, Z.
Guo, H.
Geibel, C.
Lin, H. J.
Chen, C. T.
Khomskii, D. I.
Tjeng, L. H.
Komarek, A. C.
Source :
Crystals 11(4), 378 (2021)
Publication Year :
2021

Abstract

We report on the synthesis and physical properties of cm-sized CoGeO$_3$ single crystals grown in a high pressure mirror furnace at pressures of 80~bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with T$_N$~$\sim$~33.5~K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions which reveals the presence of sizable orbital moments in CoGeO$_3$.

Details

Database :
arXiv
Journal :
Crystals 11(4), 378 (2021)
Publication Type :
Report
Accession number :
edsarx.2103.14505
Document Type :
Working Paper
Full Text :
https://doi.org/10.3390/cryst11040378