In-situ Analysis of the Effect of Residual fcc Phase and Special Grain Boundaries on the Deformation Dynamics in Pure Cobalt

Polycrystalline hcp metals - an important class of engineering materials - typically exhibit complex plasticity because of a limited number of slip systems. Among these metals, deformation is even more complicated in cobalt as it commonly contains residual fcc phase due to the incomplete martensitic fcc$\rightarrow$hcp transformation upon cooling. In this work, we employ a combination of in-situ (acoustic emission, AE) and ex-situ (scanning electron microscopy, SEM) techniques in order to examine deformation dynamics in pure polycrystalline cobalt varying in grain size and the content of residual fcc phase prepared using systematic thermal treatment and cycling. We reveal that the presence of the fcc phase and special ~71{\deg} grain boundaries between different hcp martensite variants brings about higher deformability and strength. The fcc phase provides additional slip systems and also accommodates deformation via the stress-induced fcc$\rightarrow$hcp transformation during loading. On the other hand, special boundaries enhance structural integrity and suppress the formation of critical defects. Both these non-trivial effects can dominate over the influence of grain size, being a traditional microstructural variable. The ex-situ SEM experiments further reveal that the stress-induced fcc$\rightarrow$hcp transformation is sluggish and only partial even at high strains, and it does not give rise to detectable AE signals, unlike in other materials exhibiting martensitic transformation. In turn, these insights into cobalt plasticity provide new avenues for the microstructure and performance optimization towards the desired applications through the modern concept of grain boundary engineering.
Comment: 16 pages, 13 figures, 50 references. Accepted manuscript (Materials Characterization, Elsevier)