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Photo-mediated selective deconstructive geminal dihalogenation of trisubstituted alkenes

Authors :
Han Wang
Ren Wei Toh
Xiangcheng Shi
Tonglin Wang
Xu Cong
Jie Wu
Source :
Nature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
Publication Year :
2020
Publisher :
Nature Portfolio, 2020.

Abstract

Efficient synthetic pathways to geminal dihalides are quite limited, despite their versatility as chemical building blocks. Here, the authors report a photo-mediated deconstructive fragmentation of cyclic and acyclic trisubstituted alkenes to access a variety of geminal dihalides.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
11
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.0ebe4211534f43f2911f4483ce256849
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-020-18274-2