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1-Vinylazulenes with Oxazolonic Ring-Potential Ligands for Metal Ion Detectors; Synthesis and Products Properties

Authors :
Mihaela Cristea
Liviu Bîrzan
Florea Dumitrascu
Cristian Enache
Victorita Tecuceanu
Anamaria Hanganu
Constantin Drăghici
Călin Deleanu
Alina Nicolescu
Maria Maganu
Alexandru C. Razus
Source :
Symmetry, Vol 13, Iss 7, p 1209 (2021)
Publication Year :
2021
Publisher :
MDPI AG, 2021.

Abstract

As a continuation of research on 1-vinylazulenes synthesis, on their physico–chemical properties as well as on their use as colorimetric and electrochemical materials for the detection of heavy metals ions, new compounds, 4-(azulen-1-ylmethylene)-2-phenyloxazol-5(4H)-ones, are reported. The exceptional structure of azulene moiety with symmetrical electron distribution only with respect to the x-axis gives some special chemical and physical properties to compounds in which it is inserted. Various azulene-1-carbaldehydes and hippuric acids are condensed with good yields in Erlenmeyer—Plöchl reaction conditions. The obtained 1-vinylzulenes were characterized and their UV-Vis and NMR spectra were briefly discussed.

Details

Language :
English
ISSN :
20738994
Volume :
13
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Symmetry
Publication Type :
Academic Journal
Accession number :
edsdoj.0ed32b15f0c743f5939cb6a646bc4f5c
Document Type :
article
Full Text :
https://doi.org/10.3390/sym13071209