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Triethylammonium 1,1′-binaphthyl-2,2′-diyl phosphate

Authors :
Ravikumar R. Gowda
Venkatachalam Ramkumar
Debashis Chakraborty
Source :
Acta Crystallographica Section E, Vol 66, Iss 7, Pp o1625-o1625 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the crystal structure of the title compound, C6H16N+·C20H12O4P−, an N—H...O interaction links the cation to the anion. The N atom in the triethylammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H...O interaction with one phosphate O atom of the 1,1′-binaphthyl-2,2′-diyl phosphate ligand. A bifurcated C—H...O interaction with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92 (3)°. The refined Flack parameter value of 0.50 (10) indicates inversion twinning.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.19ffee075bf646408e758ac673e54443
Document Type :
article
Full Text :
https://doi.org/10.1107/S160053681002026X