Quantifying groundwater fluxes from an aapa mire to a riverside esker formation

Water flows in peatland margins is an under-researched topic. This study examines recharge from a peatland to an esker aquifer in an aapa mire complex of northern Finland. Our objective was to study how the aapa mire margin is hydrogeologically connected to the riverside aquifer and spatial and temporal variations in the recharge of peatland water to groundwater (GW). Following geophysical studies and monitoring of the saturated zone, a GW model (MODFLOW) was used in combination with stable isotopes to quantify GW flow volumes and directions. Peatland water recharge to the sandy aquifer indicated a strong connection at the peatland–aquifer boundary. Recharge volumes from peatland to esker were high and rather constant (873 m3 d−1) and dominated esker recharge at the study site. The peat water recharging the esker boundary was rich in dissolved organic carbon (DOC). Stable isotope studies on water (δ18O, δ2H, and d-excess) from GW wells verified the recharge of DOC-rich water from peatlands to mineral soil esker. Biogeochemical analysis revealed changes from DOC to dissolved inorganic carbon in the flow pathway from peatland margin to the river Kitinen. This study highlights the importance of careful investigation of aapa mire margin areas and their potential role in regional GW recharge patterns. HIGHLIGHTS Peatland water recharge to aquifer showed connection at the peatland–aquifer boundary.; Analysis revealed changes from dissolved organic carbon to dissolved inorganic carbon in groundwater flow pathway from peatland.; Connection between an aapa mire margin and riverside esker was documented.;