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Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system

Authors :
Wan-Min Cheng
Rui Shang
Yao Fu
Source :
Nature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
Publication Year :
2018
Publisher :
Nature Portfolio, 2018.

Abstract

Production of alkenes through decarboxyolefination of carboxylates is a synthetically useful process. Here, the authors report a palladium/dual ligand-enabled decarboxylative desaturation reaction under mild irradiation conditions and apply it to the synthesis of Chondriamide A and C.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
9
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.1cef7329fb3b40f1a3e030b986befb9b
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-018-07694-w