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Tetra-μ-oxido-tetrakis{dioxido[3-(2-pyridyl)-1H-pyrazole]molybdenum(VI)}
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1074-m1074 (2009)
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, [Mo4O12(C8H7N3)4], the MoVI ion has a distorted octahedral coordination completed by two terminal O atoms, two μ-oxide atoms and two N atoms from one 3-(2-pyridyl)-1H-pyrazole ligand. It is noteworthy that in the tetranuclear unit (overline4 symmetry), any three MoVI atoms define a plane, and the fourth lies 1.8 (1) Å out of that plane. The degree of linearity of the oxide bridges between two Mo atoms is 175.38 (13)°. Moreover, the N—H group forms an intramolecular hydrogen bond (four per molecule).
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 9
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.20b8c17ba1c14ea78719d146ff12ec2c
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536809031717