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Tetra-μ-oxido-tetrakis{dioxido[3-(2-pyridyl)-1H-pyrazole]molybdenum(VI)}

Authors :
Dacheng Li
Ying Liu
Peihai Wei
Bo Hu
Xiutang Zhang
Source :
Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1074-m1074 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [Mo4O12(C8H7N3)4], the MoVI ion has a distorted octahedral coordination completed by two terminal O atoms, two μ-oxide atoms and two N atoms from one 3-(2-pyridyl)-1H-pyrazole ligand. It is noteworthy that in the tetranuclear unit (overline4 symmetry), any three MoVI atoms define a plane, and the fourth lies 1.8 (1) Å out of that plane. The degree of linearity of the oxide bridges between two Mo atoms is 175.38 (13)°. Moreover, the N—H group forms an intramolecular hydrogen bond (four per molecule).

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
9
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.20b8c17ba1c14ea78719d146ff12ec2c
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809031717