Ultraviolet‐visible‐near‐infrared light‐responsive soft materials: Fabrication, photomechanical deformation and applications

Abstract In recent years, the advances in light‐responsive soft materials with fascinating properties and functions have attracted tremendous attention, which are also enlightening when attempting to achieve the goals of complex deformations, motions, or attractive applications by precise regulation. Attractively, light is not only a clean and inexhaustible energy but also can be controlled remotely, quickly and accurately in a non‐contact way. Moreover, light‐responsive soft materials are capable of amplifying photo‐triggered molecular changes at the microscopic scale into macroscopic deformations, that is, directly converting the input light energy into the output mechanical work, therefore enabling potential applications in the field of actuators and functional devices. To date, some wonderful reviews have reported the progress in photo‐driven soft materials. However, the research progress in ultraviolet, visible (Vis) and near‐infrared (NIR) light‐driven soft materials containing azobenzene or other non‐azobenzene moieties has not been reported yet. In this review, we summarize recent progress in light‐responsive soft materials in terms of preparation methods, response wavelengths and potential applications. Firstly, the preparation methods of photoresponsive soft materials are introduced. Subsequently, photoinduced macroscopic deformations or motions are summarized, in which Vis and NIR light‐responsive behaviors are especially highlighted. Finally, the potential applications of photoresponsive soft materials are classified. To guide the future work for researchers, the existing problems and future development prospects of light‐responsive soft materials are proposed.