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Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ3N,N′,O1)cobalt(III) nitrate monohydrate

Authors :
Mouhamadou Moustapha Sow
Ousmane Diouf
Ibrahima Elhadj Thiam
Mohamed Gaye
Pascal Retailleau
Source :
Acta Crystallographica Section E, Vol 68, Iss 2, Pp m121-m122 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

In the title compound, [Co(C16H19N2O2)2]NO3·H2O, the CoIII ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by intermolecular O—H...O hydrogen bonds involving the uncoordinated water molecule and the free phenol hydroxyl group with the nitrate anion. N—H...O hydrogen bonds involving the amino groups and the nitrate anions connect the complex molecules along the c axis.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.28c2c24b51d9411dab54e663e384b794
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811055851