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Effects of Sodium Alginate on the Flotation Separation of Molybdenite From Chalcopyrite Using Kerosene as Collector
- Source :
- Frontiers in Chemistry, Vol 8 (2020)
- Publication Year :
- 2020
- Publisher :
- Frontiers Media S.A., 2020.
-
Abstract
- In this paper, the effect of sodium alginate (SA) on the flotation separation of molybdenite (MoS2) from chalcopyrite using kerosene as collector was systematically investigated. The results of single-mineral micro-flotation tests indicated that SA exhibited strong depression on chalcopyrite flotation while it imposed no impact on the floatability of molybdenite. However, in the chalcopyrite–molybdenite mixed-mineral flotation system, the presence of chalcopyrite significantly increased the depressing effect of SA on molybdenite flotation, leading to a considerable reduction in the flotation selectivity. The negative impact of chalcopyrite on the performance of SA in molybdenite flotation was eliminated by adding a certain dosage of kerosene prior to SA. A concentrate containing 53.43% of molybdenum (Mo) was obtained at 76.90% of recovery using 19 mg/L kerosene and 40 mg/L SA at pH 5.4. Zeta potential measurements indicated that the adsorption of SA on chalcopyrite surfaces was stronger than that on molybdenite surfaces, which agreed with the single-mineral flotation test results. The adsorption of SA on chalcopyrite was further confirmed to be chemisorption by Fourier-transform infrared spectroscopy (FTIR) spectra analyses. When Cu2+ appeared in solution, the flotation of molybdenite was strongly depressed by SA. Mechanism analyses indicated that more active sites were generated on molybdenite surfaces after the addition of Cu2+, thus promoting the adsorption of SA.
- Subjects :
- molybdenite
chalcopyrite
sodium alginate
Cu2+-activation
flotation
Chemistry
QD1-999
Subjects
Details
- Language :
- English
- ISSN :
- 22962646
- Volume :
- 8
- Database :
- Directory of Open Access Journals
- Journal :
- Frontiers in Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.2bb8f40af7be45e2af01d0e1cf78653a
- Document Type :
- article
- Full Text :
- https://doi.org/10.3389/fchem.2020.00242