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1,3,5-Tris{[3-(1H-benzotriazol-1-ylmethyl)phenoxy]methyl}-2,4,6-trimethylbenzene

Authors :
Bao-Ming Ji
Hong-Ji Ma
Zhi-Qiang Wang
Wan-Ling Si
Chen Xu
Source :
Acta Crystallographica Section E, Vol 64, Iss 10, Pp o1936-o1937 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the title compound, C51H45N9O3, three 1-(1H-benzotriazol-1-ylmethyl)-3-phenyloxy (bmph) ligands are bonded to the central benzene ring in an asymmetric arrangement, two bmph located on one side of the central benzene ring and the other bmph located on the opposite side of the central benzene ring. The dihedral angles between the central benzene ring and the three pendant phenoxy rings are 76.71 (14), 67.81 (13) and 70.67 (16)°. In the crystal structure, one bmph is disordered over two sites in a 0.611 (5):0.389 (5) ratio. Some of the methyl H atoms are equally disordered over two sets of sites. Intermolecular C—H...N hydrogen bonding is present in the crystal structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
10
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.2df8144a9d5347bc86af6e509bfea036
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808028845