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Ir-Catalyzed ortho-C-H Borylation of Aromatic C(sp2)-H Bonds of Carbocyclic Compounds Assisted by N-Bearing Directing Groups

Authors :
Hamad H. Al Mamari
Source :
Reactions, Vol 5, Iss 2, Pp 318-337 (2024)
Publication Year :
2024
Publisher :
MDPI AG, 2024.

Abstract

C-H borylation is a powerful strategy for the construction of C-B bonds due to the synthetic versatility of C-B bonds. Various transition metals affect the powerful functionalization of C-H bonds, of which Ir is the most common. Substrate-directed methods have enabled directed Ir-catalyzed C-H borylation at the ortho position. Amongst the powerful directing groups in Ir-catalyzed C-H borylation are N-containing carbocyclic systems. This review covers substrate-directed Ir-catalyzed ortho-C-H borylation of aromatic C(sp2)-H bonds in N-containing carbocyclic compounds, such as anilines, amides, benzyl amines, hydrazones, and triazines.

Details

Language :
English
ISSN :
2624781X
Volume :
5
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Reactions
Publication Type :
Academic Journal
Accession number :
edsdoj.2e7eb199112b48cf80952badab764f0a
Document Type :
article
Full Text :
https://doi.org/10.3390/reactions5020016