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Construction of E-pH diagram and experimental study on wet synthesis of FePO4 as the precursor of cathode materials
- Source :
- MATEC Web of Conferences, Vol 355, p 01013 (2022)
- Publication Year :
- 2022
- Publisher :
- EDP Sciences, 2022.
-
Abstract
- The preparation of FePO4 as a precursor by co-precipitation method is widely used, Due to the lack of the guidance of thermodynamic theory, The prepared FePO4 often contains impurity phase, which leads to unsatisfactory performance of LiFeO4. The E-pH diagram of Fe-P-H2O system at the temperature of 25℃ were drawn through the basic E-pH principle with a number of thermodynamic data. According to the E-pH Diagram, the pH value is approximately 2.5, and the FePO4 with less impurity can be prepared by adding proper oxidant. Base on the above mentioned condition, a simple verification experiment was carried out. The results showed that the prepared iron FePO4 had fewer impurities, which provided a theoretical basis for preparing high-performance LiFeO4.
Details
- Language :
- English, French
- ISSN :
- 2261236X
- Volume :
- 355
- Database :
- Directory of Open Access Journals
- Journal :
- MATEC Web of Conferences
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.324438be85a04d2790f88a5cf08fb2bc
- Document Type :
- article
- Full Text :
- https://doi.org/10.1051/matecconf/202235501013