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4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide
- Source :
- Acta Crystallographica Section E, Vol 70, Iss 1, Pp o6-o7 (2014)
- Publication Year :
- 2014
- Publisher :
- International Union of Crystallography, 2014.
-
Abstract
- There are two independent molecules in the asymmetric unit of the title compound, C24H22N2O4S3. In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methylphenylsulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two molecules. The thiazole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H...O interactions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent molecules into inversion dimers.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368 and 05588499
- Volume :
- 70
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.340c1f05588499e8f2dca1d178c23d9
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536813032145