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4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide

Authors :
Rubén M. Carballo
Simón Hernández-Ortega
Nayely Padilla-Montaño
Reyna Reyes-Martínez
Gumersindo Mirón-López
Source :
Acta Crystallographica Section E, Vol 70, Iss 1, Pp o6-o7 (2014)
Publication Year :
2014
Publisher :
International Union of Crystallography, 2014.

Abstract

There are two independent molecules in the asymmetric unit of the title compound, C24H22N2O4S3. In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methylphenylsulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two molecules. The thiazole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H...O interactions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent molecules into inversion dimers.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368 and 05588499
Volume :
70
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.340c1f05588499e8f2dca1d178c23d9
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536813032145