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Double dative bond between divalent carbon(0) and uranium

Authors :
Wei Su
Sudip Pan
Xiong Sun
Shuao Wang
Lili Zhao
Gernot Frenking
Congqing Zhu
Source :
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Publication Year :
2018
Publisher :
Nature Portfolio, 2018.

Abstract

While chemical bonding between carbon and the d- and p-block elements is relatively well-studied, that between carbon and the f-block elements remains comparatively poorly understood. Here, the authors synthesize a series of uranium−carbone complexes in which carbon forms an unprecedented double dative bond to uranium.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
9
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.342c125aa2476aa2e0c4da28cca06c
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-018-07377-6