JWST Reveals CO Ice, Concentrated CO2 Deposits, and Evidence for Carbonates Potentially Sourced from Ariel’s Interior

The Uranian moon Ariel exhibits a diversity of geologically young landforms, with a surface composition rich in CO _2 ice. The origin of CO _2 and other species, however, remains uncertain. We report observations of Ariel’s leading and trailing hemispheres, collected with NIRSpec (2.87–5.10 μ m) on the James Webb Space Telescope. These data shed new light on Ariel's spectral properties, revealing a double-lobed CO _2 ice scattering peak centered near 4.20 and 4.25 μ m, with the 4.25 μ m lobe possibly representing the largest CO _2 Fresnel peak yet observed in the solar system. A prominent 4.38 μ m ^13 CO _2 ice feature is also present, as is a 4.90 μ m band that results from ^12 CO _2 ice. The spectra reveal a 4.67 μ m ^12 CO ice band and a broad 4.02 μ m band that might result from carbonate minerals. The data confirm that features associated with CO _2 and CO are notably stronger on Ariel’s trailing hemisphere compared to its leading hemisphere. We compared the detected CO _2 features to synthetic spectra of CO _2 ice and mixtures of CO _2 with CO, H _2 O, and amorphous carbon, finding that CO _2 could be concentrated in deposits thicker than ∼10 mm on Ariel’s trailing hemisphere. Comparison to laboratory data indicates that CO is likely mixed with CO _2 . The evidence for thick CO _2 ice deposits and the possible presence of carbonates on both hemispheres suggests that some carbon oxides could be sourced from Ariel’s interior, with their surface distributions modified by charged particle bombardment, sublimation, and seasonal migration of CO and CO _2 from high to low latitudes.