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A compressed octahedral cobalt(II) complex in the crystal structure of diaqua[6,6′-sulfanediylbis(2,2′-bipyridine)]cobalt(II) dinitrate
- Source :
- Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 7, Pp 993-995 (2017)
- Publication Year :
- 2017
- Publisher :
- International Union of Crystallography, 2017.
-
Abstract
- The asymmetric unit of the title salt, [Co(C20H14N4S)(H2O)2](NO3)2, comprises a [Co(C20H14N4S)(H2O)2]2+ cation and two NO3− anions. In the complex, [Co(C20H14N4S)(H2O)2]2+ cation, the tetradentate 6,6′-sulfanediylbis(2,2′-bipyridine) ligand coordinates to the CoII cation in the equatorial positions, while two water molecules occupy the axial positions, forming a compressed octahedral CoN4O2 coordination sphere. The NO3− anions are linked to the [Co(C20H14N4S)(H2O)2]2+ cations via O—H...O hydrogen bonds, yielding a layered arrangement parallel to (001).
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 73
- Issue :
- 7
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.3a0065d4334c44be99022a2b2874f0f0
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2056989017008428