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Mechanism and kinetics study of vanadium leaching from landfilled metallurgical residues by ultrasonic with ozonation enhancement in a low-acid medium

Authors :
Haoyu Li
Chunhua Hu
Xinyi He
Jun Wang
Shihong Tian
Xuejun Zhu
Xuehua Mao
Source :
Ultrasonics Sonochemistry, Vol 109, Iss , Pp 106998- (2024)
Publication Year :
2024
Publisher :
Elsevier, 2024.

Abstract

Landfilled metallurgical residues are valuable raw materials for the recovery of strategic vanadium resources. However, efficient separation of vanadium from these residues is challenging due to its strong oxidation resistance and coating within silicate inclusions. To address this issue, this study proposes an enhanced leaching process utilizing the synergistic effect of O3-catalyzed ultrasonic field in a low concentration sulfuric acid system. Results show that following a 10-minute O3 and ultrasonic treatment, the direct leaching rate of vanadium experienced a remarkable 46.7 % increase. Quenching experiments revealed a hierarchical order of active species within the reaction process:⋅OH >⋅O2−> H+, with⋅OH oxidation exhibiting the most pronounced capacity for disrupting the inclusion structure. Electron Paramagnetic Resonance analysis indicated that the highest⋅OH yield arose from the combined application of ultrasound and ozone. Kinetic investigations demonstrated that the vanadium leaching process is governed by interfacial chemical reactions. The activation energy of vanadium oxidation leaching under ultrasonic-O3 conditions was determined to be 40.41 kJ/mol, representing a 20.19 % reduction compared to ultrasonic conditions alone. Through the integration of analysis, characterization, and comparative evaluations, it was discerned that the synergistic impact of ultrasonic and ozone treatments significantly enhances the breakdown of silicate inclusions by low-concentration HF, particularly in the conversion of SiOSi bonds into SiOH bonds and SiF bonds. In summary, the refined leaching methodology incorporating ozone catalysis in conjunction with ultrasonic treatment provides a new idea for the separation and extraction of refractory residual vanadium.

Details

Language :
English
ISSN :
13504177 and 98081659
Volume :
109
Issue :
106998-
Database :
Directory of Open Access Journals
Journal :
Ultrasonics Sonochemistry
Publication Type :
Academic Journal
Accession number :
edsdoj.3d463bef9dbf446d932b98081659a11b
Document Type :
article
Full Text :
https://doi.org/10.1016/j.ultsonch.2024.106998