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A Model of a Two-step Three-electron Surface Redox Reaction

Authors :
Milivoj Lovrić
Source :
Kemija u Industriji, Vol 73, Iss 5-6, Pp 221-227 (2024)
Publication Year :
2024
Publisher :
Croatian Society of Chemical Engineers, 2024.

Abstract

A theory of a two-step surface redox mechanism, involving both single-electron and two-electron transfers, is developed for cyclic voltammetry. It is assumed that the first step is kinetically controlled, while the second one is reversible. Depending on the difference in standard potentials, three types of responses appear as functions of the kinetic parameters. Calculation of the transfer coefficients and the standard rate constant is explained.

Details

Language :
English, Croatian
ISSN :
00229830 and 13349090
Volume :
73
Issue :
5-6
Database :
Directory of Open Access Journals
Journal :
Kemija u Industriji
Publication Type :
Academic Journal
Accession number :
edsdoj.3ea704ac6c39490e91d0a8caa2d41a9c
Document Type :
article
Full Text :
https://doi.org/10.15255/KUI.2023.041