Back to Search Start Over

Mechanochemical synthesis of oxygenated alkynyl carbon materials with excellent Hg(II) adsorption performance from CaC2 and carbonates

Authors :
Yingjie Li
Songping Li
Xinyi Xu
Hong Meng
Yingzhou Lu
Chunxi Li
Source :
Green Energy & Environment, Vol 8, Iss 1, Pp 275-282 (2023)
Publication Year :
2023
Publisher :
KeAi Communications Co., Ltd., 2023.

Abstract

Adsorptive removal of heavy metal ions from wastewater is very important, and the key is the development of efficient sorbents. In this work, oxygenated alkynyl carbon materials (OACMs) were synthesized via mechanochemical reaction of CaC2 and a carbonate (CaCO3, Na2CO3, or NaHCO3) at ambient temperature. The resultant OACMs are micro mesoporous carbon nanomaterials with high specific area (>648 m2 g−1), highly crosslinked texture, and rich alkynyl and oxygenated groups. The OACMs exhibit excellent Hg(II) adsorption due to the soft acid-soft base interaction between alkynyl and Hg(II), and OACM-3 derived from CaC2 and NaHCO3 has the saturated Hg(II) adsorbance of 483.9 mg g−1 along with good selectivity and recyclability. The adsorption is mainly chemisorption following the Langmuir mode. OACM-3 also shows high adsorbance for other heavy metal ions, e.g. 256.6 mg g−1 for Pb(II), 232.4 mg g−1 for Zn(II), and 198.7 mg g−1 for Cu(II). This work expands the mechnochemical reaction of CaC2 with carbonates and possibly other oxyanionic salts, provides a new synthesis approach for functional alkynyl carbon materials with excellent adsorption performance for heavy metal ions, as well as a feasible approach for CO2 resource utilization.

Details

Language :
English
ISSN :
24680257
Volume :
8
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Green Energy & Environment
Publication Type :
Academic Journal
Accession number :
edsdoj.3ff185ffd9ef49fd9261693efcc99609
Document Type :
article
Full Text :
https://doi.org/10.1016/j.gee.2021.04.007