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catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thiadiazole-κ2N2:N5]
- Source :
- Acta Crystallographica Section E, Vol 64, Iss 2, Pp m393-m393 (2008)
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography, 2008.
-
Abstract
- The title compound, [ZnCl2(C12H8N4S)]n, was obtained by crystallization of 2,5-di-4-pyridyl-1,3,4-thiadiazole with ZnCl2 in an MeOH/CHCl3 solvent system. The structure contains infinite chains of ZnCl2 units connected by the bifunctional thiadiazole ligands, with ZnII adopting a distorted tetrahedral coordination geometry. The dihedral angle between the two pyridyl rings in each ligand is 34.3 (1)°, and the dihedral angles between the thiadiazole ring and the two pyridyl rings are 18.3 (2) and 16.1 (2)°. The shortest Zn...Zn distance within each polymeric chain is 11.862 (3) Å, while the shortest interchain Zn...Zn distance is 7.057 (3) Å.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 64
- Issue :
- 2
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.440048466adf4972942fd19b28132de9
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536808001967