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Fenton process enhanced by metal sulfide for treating the actual evaporated mother liquid of gas field wastewater
- Source :
- Journal of Water Reuse and Desalination, Vol 13, Iss 2, Pp 193-204 (2023)
- Publication Year :
- 2023
- Publisher :
- IWA Publishing, 2023.
-
Abstract
- Evaporated mother liquor of gas field wastewater (EML-GFW) is a form of wastewater generated by the triple-effect evaporation treatment of gas field wastewater containing complex pollutants. In this study, four metal sulfides, CuS, ZnS, MoS2, and WS2, were used to strengthen the Fenton process in EML-GFW treatment. The optimum Fenton/ZnS process for the highest removal of TOC from EML-GFW was achieved at the initial pH of 3.0 and in a mixture of FeSO4·7H2O:ZnS:H2O2 in the ratio of 30 g/L:10 g/L:1.2 mol/L, with a TOC removal efficiency of 74.5%. The organic components analysis of EML-GFW over four distinct periods demonstrated that the presence of N,N-dimethylethanolamine (DMEA) persisted and accounted for the greatest proportion of pollutants, identifying it as the characteristic pollutant. The TOC removal mechanism by Fenton/ZnS was revealed via analysis of organic materials obtained from the Fenton/ZnS process, tert-butanol quenching experiment, and illumination experiment. ZnS-generated hole–electron pairs under illumination, which promoted the reduction of Fe3+ to Fe2+, followed by an acceleration of •OH generation, thus improving TOC removal efficiency. The Fenton/ZnS process improved the treatment of EML-GFW in the laboratory, providing strong data support and theoretical guidance for expanding this technology at the gas field project site. HIGHLIGHTS The optimization of the Fenton/ZnS process was based on the actual wastewater.; The TOC removal efficiency of EML-GFW reached 74.5% by the optimum Fenton/ZnS process.; ZnS accelerated the production of •OH, increasing the removal efficiency of TOC.; This work was meaningful for the wastewater treatment at the gas field project site.;
Details
- Language :
- English
- ISSN :
- 22201319 and 24089370
- Volume :
- 13
- Issue :
- 2
- Database :
- Directory of Open Access Journals
- Journal :
- Journal of Water Reuse and Desalination
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.442b7041eeb845e19e215384025328f2
- Document Type :
- article
- Full Text :
- https://doi.org/10.2166/wrd.2023.081